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  6. Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals

Phenylmagnesium bromide, 3M in ether, Thermo Scientific Chemicals

Catalog No. AA87326AE
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Quantity:
100 mL
500 mL

Description

Grignard reagent

Grignard reagent Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 100-58-3
Molecular Formula C6H5BrMg
Molecular Weight (g/mol) 181.32
MDL Number MFCD00000038
InChI Key ANRQGKOBLBYXFM-UHFFFAOYSA-M
Synonym phenylmagnesium bromide, bromophenylmagnesium, magnesium, bromophenyl, phmgbr, phenylmagnesiumbromide, bromo phenyl magnesium, phenyl magnesium bromide, phenylmagnesium bromide solution, 3.0 m in diethyl ether, bromomagnesiobenzene, phenyhnagnesium bromide, grignard reagent
PubChem CID 66852
SMILES Br[Mg]C1=CC=CC=C1

Specifications

Color Yellow to Brown
Density 1.14 g/mL
Odor Ether-like
Quantity 100 mL
UN Number UN3399
Sensitivity Air, light, and moisture sensitive; May form a Precipitate
Solubility Information Miscible with terahydrofuran.
IUPAC Name bromo(phenyl)magnesium
Formula Weight 181.31
Concentration or Composition (by Analyte or Components) 3M in ether
Physical Form Liquid
Chemical Name or Material Phenylmagnesium bromide
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Safety and Handling

Hazard Category H224-H314-H335-H336
Hazard Statement GHS H Statement
H224-H261-H314-H336
Extremely flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
Precautionary Statement P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
DOTInformation Transport Hazard Class: 4.3; Packaging Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA Yes
Recommended Storage Ambient temperatures; Store under Argon
SDS

RUO – Research Use Only

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